Evaluation parameters for the alkaline fuel cell oxygen electrode

Studies were made of Pt- and Au-catalyzed porous electrodes, designed for the cathode of the alkaline H2/O2 fuel cell, employing cyclic voltammetry and the floating half-cell method. The purpose was to obtain parameters from the cyclic voltammograms which could predict performance in the fuel cell. It was found that a satisfactory relationship between these two types of measurement could not be established; however, useful observations were made of relative performance of several types of carbon used as supports for noble metal catalysts and of some Au catalysts. The best half-cell performance with H2/O2 in a 35 percent KOH electrolyte at 80 C was given by unsupported fine particle Au on Teflon; this electrode is used in the Orbiter fuel cell

Complete Positivity for Mixed Unitary Categories

In this article we generalize the \CP^\infty-construction of dagger monoidal categories to mixed unitary categories. Mixed unitary categories provide a setting, which generalizes (compact) dagger monoidal categories and in which one may study quantum processes of arbitrary (infinite) dimensions. We show that the existing results for the \CP^\infty-construction hold in this more general setting. In particular, we generalize the notion of environment structures to mixed unitary categories and show that the \CP^\infty-construction on mixed unitary categories is characterized by this generalized environment structure.Comment: Lots of figure

Balancing the Tradeoff between Profit and Fairness in Rideshare Platforms During High-Demand Hours

Rideshare platforms, when assigning requests to drivers, tend to maximize profit for the system and/or minimize waiting time for riders. Such platforms can exacerbate biases that drivers may have over certain types of requests. We consider the case of peak hours when the demand for rides is more than the supply of drivers. Drivers are well aware of their advantage during the peak hours and can choose to be selective about which rides to accept. Moreover, if in such a scenario, the assignment of requests to drivers (by the platform) is made only to maximize profit and/or minimize wait time for riders, requests of a certain type (e.g. from a non-popular pickup location, or to a non-popular drop-off location) might never be assigned to a driver. Such a system can be highly unfair to riders. However, increasing fairness might come at a cost of the overall profit made by the rideshare platform. To balance these conflicting goals, we present a flexible, non-adaptive algorithm, \lpalg, that allows the platform designer to control the profit and fairness of the system via parameters $\alpha$ and $\beta$ respectively. We model the matching problem as an online bipartite matching where the set of drivers is offline and requests arrive online. Upon the arrival of a request, we use \lpalg to assign it to a driver (the driver might then choose to accept or reject it) or reject the request. We formalize the measures of profit and fairness in our setting and show that by using \lpalg, the competitive ratios for profit and fairness measures would be no worse than $\alpha/e$ and $\beta/e$ respectively. Extensive experimental results on both real-world and synthetic datasets confirm the validity of our theoretical lower bounds. Additionally, they show that \lpalg under some choice of $(\alpha, \beta)$ can beat two natural heuristics, Greedy and Uniform, on \emph{both} fairness and profit

A Note on the Intermediate Region in Turbulent Boundary Layers

We demonstrate that the processing of the experimental data for the average velocity profiles obtained by J. M. \"Osterlund (www.mesh.kth.se/$\sim$jens/zpg/) presented in [1] was incorrect. Properly processed these data lead to the opposite conclusion: they confirm the Reynolds-number-dependent scaling law and disprove the conclusion that the flow in the intermediate (`overlap') region is Reynolds-number-independent.Comment: 8 pages, includes 1 table and 3 figures, broken web link in abstract remove

Experimental confirmation of chaotic phase synchronization in coupled time-delayed electronic circuits

We report the first experimental demonstration of chaotic phase synchronization (CPS) in unidirectionally coupled time-delay systems using electronic circuits. We have also implemented experimentally an efficient methodology for characterizing CPS, namely the localized sets. Snapshots of the evolution of coupled systems and the sets as observed from the oscilloscope confirming CPS are shown experimentally. Numerical results from different approaches, namely phase differences, localized sets, changes in the largest Lyapunov exponents and the correlation of probability of recurrence ($C_{CPR}$), corroborate the experimental observations.Comment: Physical_Review_E_82_065201(R) 201

Real-time Measurement of Stress and Damage Evolution During Initial Lithiation of Crystalline Silicon

Crystalline to amorphous phase transformation during initial lithiation in (100) silicon-wafers is studied in an electrochemical cell with lithium metal as the counter and reference electrode. It is demonstrated that severe stress jumps across the phase boundary lead to fracture and damage, which is an essential consideration in designing silicon based anodes for lithium ion batteries. During initial lithiation, a moving phase boundary advances into the wafer starting from the surface facing the lithium electrode, transforming crystalline silicon into amorphous LixSi. The resulting biaxial compressive stress in the amorphous layer is measured in situ and it was observed to be ca. 0.5 GPa. HRTEM images reveal that the crystalline-amorphous phase boundary is very sharp, with a thickness of ~ 1 nm. Upon delithiation, the stress rapidly reverses, becomes tensile and the amorphous layer begins to deform plastically at around 0.5 GPa. With continued delithiation, the yield stress increases in magnitude, culminating in sudden fracture of the amorphous layer into micro-fragments and the cracks extend into the underlying crystalline silicon.Comment: 12 pages, 5 figure

Preparation and thermal decomposition of some oxomolybdenum(VI) oxalates

Anionic oxomolybdenum(VI) oxalates having the general formula A2[MoO3(C2O4] · H2O where A = K+ or NH4+ are prepared, characterized by chemical and infrared spectra and their thermal decomposition studied by DTA and TGA. A chain structure containing MoO6 octahedra linked through oxygen is proposed for the complex oxalates on the basis of i.r. absorption spectra. The ammonium compound decomposes endothermally around 270°C to give lower oxides of molybdenum which are finally oxidised to MoO3, while the final decomposition product of the potassium compound is K2MoO4